1032 lines
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HTML
1032 lines
106 KiB
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<title>Ammoniak-Spaltung durch LEDs statt Hitze - Neuartiger Lichtreaktor erleichtert Wasserstoff-Rückgewinnung aus Ammoniak - scinexx.de</title>
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<meta name="description" content="Wegbereiter zu "grünem" Wasserstoff? Forscher haben eine neue Methode gefunden, um Wasserstoff aus Ammoniak zu gewinnen – nur mithilfe von LED-Licht," />
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<meta property="og:title" content="Ammoniak-Spaltung durch LEDs statt Hitze" />
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<meta property="og:description" content="Wegbereiter zu "grünem" Wasserstoff? Forscher haben eine neue Methode gefunden, um Wasserstoff aus Ammoniak zu gewinnen – nur mithilfe von LED-Licht," />
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<meta property="og:site_name" content="scinexx | Das Wissensmagazin" />
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<meta property="article:published_time" content="2022-11-28T00:01:49+00:00" />
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<meta property="article:modified_time" content="2022-11-28T07:33:16+00:00" />
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<meta name="author" content="Nadja Podbregar" />
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<meta name="twitter:label1" content="Verfasst von" />
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<meta name="twitter:data1" content="Nadja Podbregar" />
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|
|||
|
|
<meta name="google-site-verification" content="_OFE8Z_OfdRsTZLI5s_EEvcL1zRY9_CdLh1-aciuEy8" />
|
|||
|
|
<!-- Google Webmaster-Tools -->
|
|||
|
|
<meta name="verify-v1" content="e4xUGc3jCxWKRmc2eQYj562J9MrB05NSIdt6O4oaulQ=" />
|
|||
|
|
<meta name="verify-v1" content="w/HNMi7Q9tMno6by/Hg6Co8bR7Gn9LRH0FTA24IOFHg=" />
|
|||
|
|
<!-- /Google Webmaster-Tools -->
|
|||
|
|
<meta name="theme-color" content="#EEEEEE" />
|
|||
|
|
|
|||
|
|
|
|||
|
|
<script type="text/javascript">
|
|||
|
|
var iqad_handle = 'artikel';
|
|||
|
|
if(document.documentElement.clientWidth<=1220){ iqad_handle = 'artikel_tablet'; }
|
|||
|
|
if(document.documentElement.clientWidth<768){ iqad_handle = 'artikel_small'; }
|
|||
|
|
</script>
|
|||
|
|
<script type="text/javascript">var gzipEnabled = false;</script>
|
|||
|
|
<script type="text/javascript" src="https://s3-eu-central-1.amazonaws.com/prod.iqdcontroller.iqdigital/iqd_gzip_test.js.gz"></script>
|
|||
|
|
|
|||
|
|
<script type="text/javascript">
|
|||
|
|
var iqd_mode = (function() {
|
|||
|
|
var dm = window.location.href.toLowerCase();
|
|||
|
|
return (dm.indexOf('iqdeployment=') > 1) ? dm.split('iqdeployment=')[1].split('&')[0] : 'live';
|
|||
|
|
})();
|
|||
|
|
document.write('<scr' + 'ipt src="https://s3-eu-central-1.amazonaws.com/prod.iqdcontroller.iqdigital/cdn_scinexx_dt/' + iqd_mode + '/iqadcontroller' + (function(){ return gzipEnabled ? '.js.gz' : '.js'})() +'"></scr' + 'ipt>');
|
|||
|
|
</script>
|
|||
|
|
<script type="text/javascript">
|
|||
|
|
if (typeof AdController !== "undefined") {
|
|||
|
|
AdController.setPageInfo({
|
|||
|
|
$handle : iqad_handle,
|
|||
|
|
$autoSizeFrames: true,
|
|||
|
|
level2:"energie",
|
|||
|
|
level3:"",
|
|||
|
|
keywords : "",
|
|||
|
|
tma:""
|
|||
|
|
});
|
|||
|
|
try {
|
|||
|
|
AdController.stage();
|
|||
|
|
} catch(e) {}
|
|||
|
|
}
|
|||
|
|
</script>
|
|||
|
|
<script type="text/javascript">
|
|||
|
|
if (typeof AdController !== "undefined") {
|
|||
|
|
AdController.initialize();
|
|||
|
|
}
|
|||
|
|
</script>
|
|||
|
|
|
|||
|
|
<script src="//cdn1.readspeaker.com/script/10936/webReader/webReader.js?pids=wr" type="text/javascript"></script>
|
|||
|
|
|
|||
|
|
</head>
|
|||
|
|
|
|||
|
|
<body class="post-template-default single single-post postid-263684 single-format-standard chrome herald-boxed layout-SNX">
|
|||
|
|
<a name="top"></a>
|
|||
|
|
|
|||
|
|
|
|||
|
|
|
|||
|
|
|
|||
|
|
<!-- SZM VERSION="2.0" -->
|
|||
|
|
<script type="text/javascript">
|
|||
|
|
|
|||
|
|
window.mobilecheck = function() {
|
|||
|
|
var check = false;
|
|||
|
|
(function(a){if(/(android|bb\d+|meego).+mobile|avantgo|bada\/|blackberry|blazer|compal|elaine|fennec|hiptop|iemobile|ip(hone|od)|iris|kindle|lge |maemo|midp|mmp|mobile.+firefox|netfront|opera m(ob|in)i|palm( os)?|phone|p(ixi|re)\/|plucker|pocket|psp|series(4|6)0|symbian|treo|up\.(browser|link)|vodafone|wap|windows ce|xda|xiino/i.test(a)||/1207|6310|6590|3gso|4thp|50[1-6]i|770s|802s|a wa|abac|ac(er|oo|s\-)|ai(ko|rn)|al(av|ca|co)|amoi|an(ex|ny|yw)|aptu|ar(ch|go)|as(te|us)|attw|au(di|\-m|r |s )|avan|be(ck|ll|nq)|bi(lb|rd)|bl(ac|az)|br(e|v)w|bumb|bw\-(n|u)|c55\/|capi|ccwa|cdm\-|cell|chtm|cldc|cmd\-|co(mp|nd)|craw|da(it|ll|ng)|dbte|dc\-s|devi|dica|dmob|do(c|p)o|ds(12|\-d)|el(49|ai)|em(l2|ul)|er(ic|k0)|esl8|ez([4-7]0|os|wa|ze)|fetc|fly(\-|_)|g1 u|g560|gene|gf\-5|g\-mo|go(\.w|od)|gr(ad|un)|haie|hcit|hd\-(m|p|t)|hei\-|hi(pt|ta)|hp( i|ip)|hs\-c|ht(c(\-| |_|a|g|p|s|t)|tp)|hu(aw|tc)|i\-(20|go|ma)|i230|iac( |\-|\/)|ibro|idea|ig01|ikom|im1k|inno|ipaq|iris|ja(t|v)a|jbro|jemu|jigs|kddi|keji|kgt( |\/)|klon|kpt |kwc\-|kyo(c|k)|le(no|xi)|lg( g|\/(k|l|u)|50|54|\-[a-w])|libw|lynx|m1\-w|m3ga|m50\/|ma(te|ui|xo)|mc(01|21|ca)|m\-cr|me(rc|ri)|mi(o8|oa|ts)|mmef|mo(01|02|bi|de|do|t(\-| |o|v)|zz)|mt(50|p1|v )|mwbp|mywa|n10[0-2]|n20[2-3]|n30(0|2)|n50(0|2|5)|n7(0(0|1)|10)|ne((c|m)\-|on|tf|wf|wg|wt)|nok(6|i)|nzph|o2im|op(ti|wv)|oran|owg1|p800|pan(a|d|t)|pdxg|pg(13|\-([1-8]|c))|phil|pire|pl(ay|uc)|pn\-2|po(ck|rt|se)|prox|psio|pt\-g|qa\-a|qc(07|12|21|32|60|\-[2-7]|i\-)|qtek|r380|r600|raks|rim9|ro(ve|zo)|s55\/|sa(ge|ma|mm|ms|ny|va)|sc(01|h\-|oo|p\-)|sdk\/|se(c(\-|0|1)|47|mc|nd|ri)|sgh\-|shar|sie(\-|m)|sk\-0|sl(45|id)|sm(al|ar|b3|it|t5)|so(ft|ny)|sp(01|h\-|v\-|v )|sy(01|mb)|t2(18|50)|t6(00|10|18)|ta(gt|lk)|tcl\-|tdg\-|tel(i|m)|tim\-|t\-mo|to(pl|sh)|ts(70|m\-|m3|m5)|tx\-9|up(\.b|g1|si)|utst|v400|v750|veri|vi(rg|te)|vk(40|5[0-3]|\-v)|vm40|voda|vulc|vx(52|53|60|61|70|80|81|83|85|98)|w3c(\-| )|webc|whit|wi(g |nc|nw)|wmlb|wonu|x700|yas\-|your|zeto|zte\-/i.test(a.substr(0,4))) check = true;})(navigator.userAgent||navigator.vendor||window.opera);
|
|||
|
|
return check;
|
|||
|
|
};
|
|||
|
|
|
|||
|
|
var iam_site = 'scinexx';
|
|||
|
|
var iam_code= 'news';
|
|||
|
|
var iam_sv = 'in';
|
|||
|
|
var iam_dn = 'data-4754325bf6.scinexx.de';
|
|||
|
|
|
|||
|
|
if(window.mobilecheck() === true){
|
|||
|
|
iam_site = "mobscexx";
|
|||
|
|
iam_code = "scinexx_" + iam_code;
|
|||
|
|
iam_sv='mo';
|
|||
|
|
iam_dn = 'data-e807969afb.scinexx.de';
|
|||
|
|
|
|||
|
|
}
|
|||
|
|
|
|||
|
|
var iam_data = {
|
|||
|
|
"st":iam_site, // site/domain
|
|||
|
|
"cp":iam_code, // code
|
|||
|
|
"sv":iam_sv, // Es wird eine Befragungseinladung ausgeliefert
|
|||
|
|
"co":"", // comment
|
|||
|
|
"sc":"yes"
|
|||
|
|
}
|
|||
|
|
|
|||
|
|
/*
|
|||
|
|
iom.c(iam_data);
|
|||
|
|
*/
|
|||
|
|
|
|||
|
|
</script>
|
|||
|
|
<!--/SZM -->
|
|||
|
|
|
|||
|
|
|
|||
|
|
<script type='text/javascript'>
|
|||
|
|
IOMm('configure', { st: iam_site, dn: iam_dn, mh:5 });
|
|||
|
|
IOMm('pageview', { cp: iam_code });
|
|||
|
|
IOMm('3p', 'qds');
|
|||
|
|
</script>
|
|||
|
|
|
|||
|
|
|
|||
|
|
|
|||
|
|
<div id="iqadtileOOP-parent"><div id="iqadtileOOP" class=""><script type="text/javascript">AdController.render('iqadtileOOP');</script></div></div>
|
|||
|
|
|
|||
|
|
<div id="iqd_mainAd" >
|
|||
|
|
<div id="iqd_align_Ad">
|
|||
|
|
<div id="iqd_topAd">
|
|||
|
|
<div id="iqadtile1-parent" >
|
|||
|
|
<div id="iqadtile1" >
|
|||
|
|
|
|||
|
|
<!-- begin ad tag (tile=1) -->
|
|||
|
|
<script type="text/javascript">
|
|||
|
|
if (typeof AdController !== 'undefined') { AdController.render('iqadtile1'); }
|
|||
|
|
</script>
|
|||
|
|
<!-- end ad tag -->
|
|||
|
|
</div>
|
|||
|
|
</div><div id="iqd_rightAd" class="hide-mobile">
|
|||
|
|
<div id="iqadtile2">
|
|||
|
|
<div class="ad-disclaimer kv-iqadtile1-disclaimer">Anzeige</div>
|
|||
|
|
<!-- begin ad tag (tile=2) -->
|
|||
|
|
<script type="text/javascript">
|
|||
|
|
if (typeof AdController !== 'undefined') { AdController.render('iqadtile2'); };
|
|||
|
|
</script>
|
|||
|
|
<!-- end ad tag -->
|
|||
|
|
</div>
|
|||
|
|
</div> </div>
|
|||
|
|
</div>
|
|||
|
|
</div>
|
|||
|
|
|
|||
|
|
<header id="header" class="herald-site-header ">
|
|||
|
|
|
|||
|
|
<div class="header-middle herald-header-wraper hidden-xs hidden-sm">
|
|||
|
|
<div class="container">
|
|||
|
|
<div class="row">
|
|||
|
|
<div class="col-lg-12 hel-el">
|
|||
|
|
|
|||
|
|
<div class="hel-l herald-go-hor" style="opacity: 1; position: absolute;
|
|||
|
|
top: 13.5px;">
|
|||
|
|
<div class="site-branding">
|
|||
|
|
<span class="site-title h1"><a href="/" title="www.scinexx.de Home" rel="home"><img class="herald-logo" id="main-logo" src="https://www.scinexx.de/wp-content/themes/konradin-wissenschaft/assets/images/scinexx.png" alt="Scinexx" width="352" height="85"></a><img class="herald-logo-tagline" id="tagline-logo" src="https://www.scinexx.de/wp-content/themes/konradin-wissenschaft/assets/images/das_wissensmagazin.png" alt="das wissensmagazin" width="400" height="45" style="margin-top: 48px; margin-left: 30px;"></span>
|
|||
|
|
|
|||
|
|
</div>
|
|||
|
|
</div>
|
|||
|
|
|
|||
|
|
|
|||
|
|
|
|||
|
|
|
|||
|
|
|
|||
|
|
<style>
|
|||
|
|
.header-meta{
|
|||
|
|
position: absolute; top: 18px; opacity: 1;
|
|||
|
|
right: 5px;
|
|||
|
|
color: #8D8278;
|
|||
|
|
text-align: right;
|
|||
|
|
}
|
|||
|
|
.header-meta a {
|
|||
|
|
color: #8D8278;
|
|||
|
|
}
|
|||
|
|
</style>
|
|||
|
|
<div class="header-meta">
|
|||
|
|
<span class="herald-calendar" style="margin-right: 10px !important;"><i class="fa fa-calendar"></i>12. Dezember 2022</span>
|
|||
|
|
<br><br>
|
|||
|
|
<ul id="menu-snx-social" class="herald-soc-nav"><li id="menu-item-4450" class="menu-item menu-item-type-custom menu-item-object-custom menu-item-4450"><a target="_blank" rel="noopener" href="https://www.facebook.com/scinexx"><span class="herald-social-name">Facebook</span></a></li>
|
|||
|
|
<li id="menu-item-228639" class="menu-item menu-item-type-custom menu-item-object-custom menu-item-228639"><a target="_blank" rel="noopener" href="https://www.instagram.com/scinexx_wissensmagazin/"><span class="herald-social-name">Instagram</span></a></li>
|
|||
|
|
<li id="menu-item-4452" class="menu-item menu-item-type-custom menu-item-object-custom menu-item-4452"><a target="_blank" rel="noopener" href="https://twitter.com/scinexx"><span class="herald-social-name">Twitter</span></a></li>
|
|||
|
|
<li id="menu-item-4453" class="menu-item menu-item-type-custom menu-item-object-custom menu-item-4453"><a target="_blank" rel="noopener" href="https://www.youtube.com/user/scinexx?sub_confirmation=1"><span class="herald-social-name">Youtube</span></a></li>
|
|||
|
|
<li id="menu-item-4454" class="menu-item menu-item-type-custom menu-item-object-custom menu-item-4454"><a target="_blank" rel="noopener" href="http://feeds.feedburner.com/scinexx"><span class="herald-social-name">RSS</span></a></li>
|
|||
|
|
</ul>
|
|||
|
|
|
|||
|
|
|
|||
|
|
</div>
|
|||
|
|
|
|||
|
|
|
|||
|
|
|
|||
|
|
</div>
|
|||
|
|
</div>
|
|||
|
|
</div>
|
|||
|
|
</div> <div class="header-bottom herald-header-wraper hidden-sm hidden-xs">
|
|||
|
|
<div class="container">
|
|||
|
|
<div class="row">
|
|||
|
|
<div class="col-lg-12 hel-el">
|
|||
|
|
|
|||
|
|
<div class="hel-l">
|
|||
|
|
<nav class="main-navigation herald-menu">
|
|||
|
|
|
|||
|
|
<ul id="menu-snx-main" class="menu"><li id="menu-item-79461" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-home menu-item-79461"><a href="https://www.scinexx.de/">Home</a><li id="menu-item-4442" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4442"><a href="https://www.scinexx.de/geowissen/">Geowissen</a><li id="menu-item-4439" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4439"><a href="https://www.scinexx.de/biowissen/">Biowissen</a><li id="menu-item-4445" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4445"><a href="https://www.scinexx.de/medizin/">Medizin</a><li id="menu-item-4441" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4441"><a href="https://www.scinexx.de/energie/">Energie</a><li id="menu-item-4447" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4447"><a href="https://www.scinexx.de/technik/">Technik</a><li id="menu-item-255344" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-255344"><a href="https://www.scinexx.de/physik/">Physik</a><li id="menu-item-4444" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4444"><a href="https://www.scinexx.de/kosmos/">Kosmos</a><li id="menu-item-255345" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-255345"><a href="https://www.scinexx.de/archaeologie/">Archäologie</a><li id="menu-item-255343" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-255343"><a href="https://www.scinexx.de/psychologie/">Psychologie</a><li id="menu-item-4440" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4440"><a href="https://www.scinexx.de/dossiers/">Dossiers</a></ul> </nav> </div>
|
|||
|
|
|
|||
|
|
|
|||
|
|
<div class="hel-r">
|
|||
|
|
<div class="herald-menu-popup-search">
|
|||
|
|
<span class="fa fa-search"></span>
|
|||
|
|
<div class="herald-in-popup">
|
|||
|
|
<form class="herald-search-form" action="https://www.scinexx.de/" method="get">
|
|||
|
|
<input name="s" class="herald-search-input" type="text" value="" placeholder="suchen" /><button type="submit" class="herald-search-submit"></button>
|
|||
|
|
</form>
|
|||
|
|
|
|||
|
|
</div>
|
|||
|
|
</div> </div>
|
|||
|
|
|
|||
|
|
|
|||
|
|
|
|||
|
|
</div>
|
|||
|
|
</div>
|
|||
|
|
</div>
|
|||
|
|
</div> <div class="header-top hidden-xs hidden-sm">
|
|||
|
|
<div class="container">
|
|||
|
|
<div class="row">
|
|||
|
|
<div class="col-lg-12">
|
|||
|
|
|
|||
|
|
<div class="hel-l">
|
|||
|
|
<nav class="secondary-navigation herald-menu">
|
|||
|
|
<ul id="menu-snx-themen" class="menu"><li id="menu-item-4464" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4464"><a href="https://www.scinexx.de/earthview/">Earthview</a></li>
|
|||
|
|
<li id="menu-item-253906" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-253906"><a href="https://www.scinexx.de/medien-tipps/">Medien-Tipps</a></li>
|
|||
|
|
<li id="menu-item-4465" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4465"><a href="https://www.scinexx.de/medien-galerie/">Galerie</a></li>
|
|||
|
|
<li id="menu-item-4466" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4466"><a href="https://www.scinexx.de/lernwelten/">Lernwelten</a></li>
|
|||
|
|
<li id="menu-item-4467" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4467"><a href="https://www.scinexx.de/schlagzeilen/">Schlagzeilen</a></li>
|
|||
|
|
<li id="menu-item-4463" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4463"><a href="https://www.scinexx.de/business/">BusinessNews</a></li>
|
|||
|
|
<li id="menu-item-4469" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-4469"><a href="https://www.scinexx.de/videos/">Videos</a></li>
|
|||
|
|
<li id="menu-item-253901" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-253901"><a href="https://www.scinexx.de/jobs/">Jobs</a></li>
|
|||
|
|
<li id="menu-item-253902" class="menu-item menu-item-type-post_type menu-item-object-page menu-item-253902"><a href="https://www.scinexx.de/newsletter/">Newsletter</a></li>
|
|||
|
|
<li id="menu-item-253903" class="menu-item menu-item-type-custom menu-item-object-custom menu-item-253903"><a href="https://www.scinexx.de/shopping/">Shop</a></li>
|
|||
|
|
</ul></nav>
|
|||
|
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<article id="post-263684" class="herald-single post-263684 post type-post status-publish format-standard has-post-thumbnail hentry category-energie category-technik tag-ammoniak tag-ammoniakspaltung tag-energietraeger tag-katalyse tag-lichtreaktor tag-photokatalyse tag-wasserstoff thema-chemie" data-thumbnail="https://www.scinexx.de/wp-content/uploads/a/m/ammoniakg-300x200.jpg">
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<h1 class="entry-title h1 rs-speak" id="headline">Ammoniak-Spaltung durch LEDs statt Hitze</h1>
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<h2 class="meta-category rs-speak" id="subline">
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Neuartiger Lichtreaktor erleichtert Wasserstoff-Rückgewinnung aus Ammoniak
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</h2>
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<div class="entry-meta"><div class="meta-item herald-date"><span class="updated">28. November 2022</span></div></div>
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<span><a data-fancybox data-options='{"buttons":["fullScreen", "close"]}' href="https://www.scinexx.de/wp-content/uploads/a/m/ammoniakg.jpg"><img width="990" height="577" src="https://www.scinexx.de/wp-content/uploads/a/m/ammoniakg-990x577.jpg" class="attachment-herald-lay-single size-herald-lay-single wp-post-image" alt="Lichtreaktor" decoding="async" srcset="https://www.scinexx.de/wp-content/uploads/a/m/ammoniakg-990x577.jpg 990w, https://www.scinexx.de/wp-content/uploads/a/m/ammoniakg-300x175.jpg 300w, https://www.scinexx.de/wp-content/uploads/a/m/ammoniakg-768x448.jpg 768w, https://www.scinexx.de/wp-content/uploads/a/m/ammoniakg.jpg 1000w" sizes="(max-width: 990px) 100vw, 990px" /></a></span>
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<figure class="wp-caption-text">In diesem Lichtreaktor kann Wasserstoff aus Ammoniak gewonnen werden – nur mithilfe von LEDs und einem Kupfer-Eisen-Katalysator. © Brandon Martin/ Rice University</figure>
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<p><strong>Wegbereiter zu „grünem“ Wasserstoff? Forscher haben eine neue Methode gefunden, um Wasserstoff aus Ammoniak zu gewinnen – nur mithilfe von LED-Licht, Eisen und Kupfer. Anders als bei der gängigen Ammoniak-Spaltung benötigt diese Photokatalyse keine starke Hitze oder teure Platinmetalle, wie das Team in „Science“ berichtet. Das könnte den künftigen Einsatz von Ammoniak als Transport- und Speichermedium für „grünen“ Wasserstoff deutlich erleichtern.</strong><span id="more-263684"></span></p>
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<p><a href="https://www.scinexx.de/dossier/wasserstoff-kommt-der-grosse-boom/">Wasserstoff</a> gilt als Energieträger der Zukunft. Er kann klimafreundlich durch <a href="https://www.scinexx.de/news/energie/erster-power-to-x-atlas/">Elektrolyse</a> von Wasser mithilfe von Sonnen- und Windstrom gewonnen werden und dabei zugleich Stromschwankungen ausgleichen. Doch um den Wasserstoff effizient speichern und transportieren zu können, muss er extrem heruntergekühlt und verflüssigt oder aber in chemisch gebundene Form gebracht werden. Als vielversprechender Kandidat für letzteres gilt flüssiges Ammoniak (NH<sub>3</sub>), das zwar korrosiv und giftig ist, aber nur auf minus 40 Grad gekühlt werden muss.</p>
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<p>Das Problem jedoch: Um Ammoniak wieder in Stickstoff und Wasserstoff aufzuspalten, benötigt man 400 bis 600 Grad Hitze und entsprechende Energie. Zwar können Katalysatoren aus Platin, Ruthenium, Ruthenium oder Palladium die Reaktionstemperatur senken, sie sind aber teuer und rar.</p>
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<figure id="attachment_263688" class="wp-caption alignright" style="width: 285px;"><a href="https://www.scinexx.de/wp-content/uploads/a/m/ammoniak2g.jpg" data-lightbox="https://www.scinexx.de/wp-content/uploads/a/m/ammoniak2g.jpg"><img decoding="async" loading="lazy" class="size-medium wp-image-263688" src="https://www.scinexx.de/wp-content/uploads/a/m/ammoniak2g-285x300.jpg" alt="LED-REaktor" width="285" height="300" srcset="https://www.scinexx.de/wp-content/uploads/a/m/ammoniak2g-285x300.jpg 285w, https://www.scinexx.de/wp-content/uploads/a/m/ammoniak2g-972x1024.jpg 972w, https://www.scinexx.de/wp-content/uploads/a/m/ammoniak2g-768x809.jpg 768w, https://www.scinexx.de/wp-content/uploads/a/m/ammoniak2g-990x1043.jpg 990w, https://www.scinexx.de/wp-content/uploads/a/m/ammoniak2g.jpg 1000w" sizes="(max-width: 285px) 100vw, 285px" /></a><figcaption class="wp-caption-text">Aufbau des LED-Reaktors zur Ammoniak-Spaltung. <span class="img-copyright">© Syzygy Plasmonics Inc </span></figcaption></figure>
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<h3>Eisen und Kupfer als Spaltungshelfer</h3>
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<p>Eine günstigere Alternative haben nun Yigao Yuan von der Rice University on Houston und seine Kollegen entwickelt. Statt das Ammoniak durch die klassische thermische Reaktion zu cracken, nutzen sie sogenannte plasmonische Photokatalysatoren. Diese meist aus metallischen Nanopartikeln bestehenden Reaktionshelfer wirken wie winzige Antennen, die die Energie des einfallenden Lichts bündeln und dadurch Elektronen des Materials kurzzeitig stark anregen. Ein zweites Metall dient als vorübergehender Partner für Stickstoff und ermöglicht so die Abspaltung des Wasserstoffs.</p>
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<p>Für ihre Studie erzeugten die Forschenden zunächst einen Photokatalysator mit Kupfer als Lichtantenne und Eisen als chemischen Spaltungshelfer. Diese Partikel gaben sie zusammen mit Ammoniak in einen Testreaktor und führten in einem ersten Durchgang Licht in Form von Laserpulsen zu. Tatsächlich kam eine Ammoniakspaltung in Gang. „Unter Lichtzufuhr zeigte der Kupfer-Eisen-Katalysator eine Reaktivität und Effizienz, die mit der des gängigen Katalysators Kupfer-Ruthenium vergleichbar ist“, berichtet Yuans Kollege Hossein Robatjazi.</p><div id="iqadtile4-parent"><div id="iqadtile4" class=""><div class="ad-disclaimer kv-iqadtile4-disclaimer">Anzeige</div><script type="text/javascript">AdController.render('iqadtile4');</script></div></div>
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<h3>Lichtreaktor mit LED-Beleuchtung</h3>
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<p>Doch funktioniert dies auch in größerem Maßstab – und ohne aufwendige Lasertechnologie? Um das zu testen, verwendete das Forschungsteam nun einen 500-fach größeren Reaktor, dessen Lichtquelle aus einem dichten Array von LEDs der Wellenlänge 470 Nanometer bestand. Das Ammoniak wurde durch zwei Reaktionsröhren kontinuierlich am Katalysator vorbei durch den mit insgesamt 140 Watt beleuchteten Reaktor geleitet.</p>
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<p>Das Ergebnis: „Der Kupfer-Eisen-Katalysator zeigt auch unter LED-Beleuchtung eine sehr hohe photokatalytische Reaktivität, mit einer 72-prozentigen Ammoniak-Umwandlung und einer Ausbeute von 14 Gramm Wasserstoff pro Tag“, berichtet das Team. Bei erhöhtem Durchfluss von Ammoniak ließ sich die Wasserstoffproduktion auf 18 Gramm pro Tag steigern. Diese Ammoniakspaltung fand allein mit der Energie der LEDs und bei Raumtemperatur statt, ohne zusätzliches Aufheizen.</p>
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<p>„Dies ist der erste Bericht in der Fachliteratur, der zeigt, dass sich Wasserstoffgas in Grammmengen auch durch eine Photokatalyse mit LEDs aus Ammoniak gewinnen lässt“, sagt Seniorautorin Naomi Halas von der Rice University. Noch benötigt dieses Verfahren zwar mehr Strom als gängige Ammoniak-Cracker. Das Team erwartet aber, dass der Energieaufwand mit weiterer Optimierung und Skalierung bis auf wenige Kilowattstunden pro Kilogramm Wasserstoff sinken wird.</p>
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<p><iframe loading="lazy" title="YouTube video player" src="https://www.youtube.com/embed/EqZLykm0EXM" allowfullscreen="allowfullscreen" width="560" height="315" frameborder="0"></iframe></p>
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<div class="video-caption" style="margin-top: -3rem;"><span class="video-caption">So funktioniert die Wasserstoffgewinnung aus Ammoniak im Lichtreaktor.</span><span class="video-copyright">© Brandon Martin/ Rice University </span></div>
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<h3>Grüner Wasserstoff – dezentral und günstig</h3>
|
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<p>Nach Ansicht der Wissenschaftler eröffnet dieses Verfahren damit neue Möglichkeiten, die Ammoniakspaltung günstiger und dezentraler zu mache. Denn statt in großen Cracker-Anlagen könnte der Wasserstoff auch in vielen kleinen, einfacheren Reaktoren aus dem Ammoniak wiedergewonnen werden. „Unsere Entdeckung ebnet den Weg zu nachhaltigem, kostengünstigem Wasserstoff, der lokal statt in zentralisierten Anlagen produziert wird“, sagt Halas‘ Kollege Peter Nordlander.</p><div id="iq-artikelanker-parent"><div id="iq-artikelanker" class=""><script type="text/javascript">AdController.render('iq-artikelanker');</script></div></div>
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<p>„Wasserstoff kann nur dann zum sauberen Brennstoff werden, wenn er günstig, einfach zu speichern und wiederzugewinnen ist“, ergänzt Halas. „Mit unserem Ansatz nähern wir uns diesem Ziel, indem wir Wasserstoff nach Bedarf und mithilfe von reichlich verfügbaren Materialien und Leuchtdioden aus einem Speichermedium wiedergewinnen können.“ (Science, 2022; <a href="https://www.science.org/doi/10.1126/science.abn5636" target="_blank" rel="noopener">doi: 10.1126/science.abn5636</a>)</p>
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<p>Quelle: Science, Rice University, Princeton University</p>
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<span class="entry-meta meta-small">28. November 2022</span>
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<p class="entry-meta meta-small"> - Nadja Podbregar</p>
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<article class="herald-lay-g post-264053 post type-post status-publish format-standard has-post-thumbnail hentry category-physik tag-atomorbital tag-ausrichtung tag-elektronenspin tag-festkoerper tag-kristallgitter tag-nullpunkt tag-quantenzustand tag-spinfluessigkeit thema-physik">
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